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Inicio  /  Coatings  /  Vol: 9 Par: 11 (2019)  /  Artículo
ARTÍCULO
TITULO

A Surface Modifier for the Production of Selectively Activated Amino Surface Groups

Kirill Puchnin    
Vitaliy Grudtsov    
Maria Andrianova    
Stanislav Bezzubov and Alexander Kuznetsov    

Resumen

The formation of self-assembled monolayers with the possibility of selective activation is an important goal of surface chemistry. In this work, a new surface modifier which creates amino surfaces based on aminopropylsilatrane (APS) with a protected amino group was obtained. The utilization of protected APS allows producing a self-assembled monolayer (SAM) and obtaining reactive surface amino groups at distinct times. Furthermore, a precise selective deprotection with a further modification of the activated amino groups could be performed without affecting the protected groups. To demonstrate the practical applicability of this modifier, a trinitrotoluene-sensitive sensor based on an ion-sensitive field-effect transistor (ISFET) was obtained.