ARTÍCULO
TITULO

Development of Photocatalytically Active Anodized Layers by a Modified Phosphoric Acid Anodizing Process for Air Purification

Stephan Lederer    
Sigrid Benfer    
Jonathan Bloh    
Rezan Javed    
Aneta Pashkova and Wolfram Fuerbeth    

Resumen

One of the key urban air quality issues is pollution by nitrogen oxides (NOx" role="presentation" style="position: relative;">xx x ). To reduce NOx" role="presentation" style="position: relative;">xx x , facade cladding could be provided with photocatalytic properties by incorporating titanium dioxide nanoparticles. For this purpose, a modified phosphoric acid anodizing process (MPAA) was developed for the facade alloy EN AW-5005, in which highly ordered anodized structures with a low degree of arborization and tortuosity were produced. Pore widths between 70 nm and 150 nm and layer thicknesses of about 2?3 μ" role="presentation" style="position: relative;">µµ µ m were obtained. The subsequent impregnation was carried out by dip coating from water-based systems. Depending on the dip-coating parameters and the suspension used, the pores can be filled up to 60% with the TiO2" role="presentation" style="position: relative;">22 2 nanoparticles. Photocatalytic tests according to ISO 22197-1 certify a high photocatalytic activity was obtained with rPCE values > 8 and with rPCE > 2, achieving ?photocatalytically active for air purification?. Tests on the corrosion resistance of the anodized coatings with a commercially available aluminum and facade cleaner confirm a protective effect of the anodized coatings when compared with nonanodized aluminum material, as well as with compacted anodized layers.

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