Resumen
Dielectric ceramic capacitors have attained considerable attention due to their energy storage performance in the field of advanced high/pulsed power capacitors. For such a purpose, configurationally disordered composite material engineering, with the substitution of suitable oxide cations at a single lattice site have demonstrated a strong dielectric relaxor phase with the ability to show high performance capacitive properties. Herein, two prominent high-entropy ceramics systems (Ba0.2Na0.2K0.2A0.2Bi0.2)TiO3, (with A = La and Mg) were fabricated to evaluate their structural, ferroelectric and dielectric properties. XRD patterns and Rietveld refinement of the XRD analysis confirmed the cubic structure Pm3¯m" role="presentation" style="position: relative;">????3_??Pm3¯m
P
m
3
¯
m
space group of the ceramics. The relative dielectric analysis of Ba0.2Na0.2K0.2La0.2Bi0.2TiO3 (BNKLBT) and Ba0.2Na0.2K0.2Mg0.2Bi0.2TiO3 (BNKMBT) ceramics were demonstrated with relaxor ferroelectric behavior having diffusion coefficients of 1.617 and 1.753, respectively. Moreover, BNKLBT and BNLMBT ceramics presented better stored energy density (1.062 J/cm3 and 0.8855 J/cm3, respectively) and high energy conversion efficiency (80.27% and 82.38%, respectively) at an electric field of 100 kV/cm. The results clearly demonstrate that such high-entropy configured ceramics have the potential to be used in efficient energy storage devices.