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Inicio  /  Applied Sciences  /  Vol: 11 Par: 6 (2021)  /  Artículo
ARTÍCULO
TITULO

Decomposition Factor Analysis Based on Virtual Experiments throughout Bayesian Optimization for Compost-Degradable Polymers

Ryo Yamawaki    
Akiyo Tei    
Kengo Ito and Jun Kikuchi    

Resumen

Bio-based polymers have been considered as an alternative to oil-based materials for their ?carbon-neutral? environmentally degrative features. However, degradation is a complex system in which environmental factors and preparation conditions are involved, and the relationship between degradation and these factors/conditions has not yet been clarified. Moreover, an efficient system that addresses multiple degradation factors has not been developed for practical use. Thus, we constructed a decomposition degree predictive model to explore degradation factors based on analytical data and experimental conditions. The predictive model was constructed by machine learning using a dataset. The objective variable was the molecular weight, and the explanatory variables were the moisture content in a compost environment, degradation period, degree of crystallinity pre-experiment, and features of solid-state nuclear magnetic resonance spectra. The good accuracy of this predictive model was confirmed by statistical variables. The moisture content in the compost environment was a critical factor for considering initial degradation; specific scores revealed the contribution of degradation factors. Furthermore, the optimum decomposition degree, various analytical values, and experimental conditions were predictable when this predictive model was combined with Bayesian optimization. Information obtained from virtual experiments is expected to promote the material design and development of bio-based plastics.

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